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Natural
Refrigerant

The future-proof path

Why industry is switching to natural refrigerants

Natural refrigerants such as CO₂, ammonia and propane are rapidly gaining importance in industrial refrigeration technology. The reason lies in their very low or non-existent global warming potential (GWP) – and in the European F-Gas Regulation, which is increasingly restricting climate-damaging synthetic refrigerants (F-gases/HFCs).

Anyone planning or modernising a refrigeration system today is making a an investment-secure and environmentally friendly decision: independent of shrinking HFC quotas, with high efficiency and excellent suitability for heat recovery.

the three most important

CO₂, ammonia and propane at a glance

CO₂ (R744)

GWP 1

A1 — non-flammable, non-toxic

Carbon dioxide is the reference refrigerant: its global warming potential (GWP) of 1 defines the scale. It is non-flammable and non-toxic, but operates at high working pressures and with a high volumetric cooling capacity.

Typical Areas of Application

  • Commercial and deep-freeze refrigeration (supermarket, food)
  • heat recovery and heat pumps
  • data centres and industrial process cooling

Ammonia (R717)

GWP 0

B2L — toxic, mildly flammable

Ammonia has been the most efficient refrigerant in industrial refrigeration for over a hundred years — with a GWP of 0 and no ozone depletion potential. As it is toxic and flammable at higher concentrations, it requires a well-thought-out safety and system concept.

Typical Areas of Application

  • Large industrial cooling capacities
  • Food production and logistics
  • process cooling with high efficiency

Propane (R290)

GWP 0,02

A3 — flammable, non-toxic

Propane is convincing due to its excellent thermodynamic properties and very high efficiency at a GWP of 0.02. As a flammable refrigerant, it is used safely through charge quantity limitation and a suitable safety concept.

Typical Areas of Application

  • Compact chillers and chiller units
  • heat pumps with high flow temperatures
  • Systems with limited space requirements

GWP = Global Warming Potential (100 years; CO₂ = 1 as reference) according to Regulation (EU) 2024/573, Annex VI, based on the Sixth IPCC Assessment Report. Older sources cite a value of 3 for propane from the Fourth Assessment Report. Safety classifications according to ASHRAE 34 / DIN EN 378.

The F-Gas Regulation is driving change

The EU F-Gas Regulation is progressively reducing the available quantity of partially fluorinated refrigerants (HFCs) and restricting the use of high-GWP refrigerants in new systems. For operators, this means rising prices and decreasing availability of synthetic refrigerants – along with increasing legal and planning uncertainty.

Natural refrigerants are not affected by this scarcity. They safeguard system operation in the long term and make investments future-proof – a key argument even at the planning stage.

At a glance

Advantages of natural refrigerants

Climate-friendly

Very low to zero global warming potential – a direct contribution to CO₂ reduction.

Future-proof

Independent of F-Gas scarcity – long-term availability and investment security.

Highly efficient

Excellent thermodynamic properties – low operating costs and good heat recovery.

Proven

A technology proven over decades – reliably in use with the right safety concept.

Planning a refrigeration system with natural refrigerants?

KSI Kältetechnik plans, builds and maintains industrial refrigeration systems with natural refrigerants – from the energy concept through plant engineering to 24/7 service.